| Saturday 28th July 2012 | |||
| First Round | |||
| Annan Athletic | 1-0 | Livingston | |
| Berwick Rangers | 2-2 | Queen's Park | aet |
| (Queen's Park won on penalties) | |||
| Clyde | 0-1 | Partick Thistle | |
| Cowdenbeath | 1-1 | Alloa Athletic | aet |
| (Cowdenbeath won on penalties) | |||
| Dumbarton | 0-1 | Queen of the South | |
| East Stirlingshire | 3-1 | Ayr United | |
| Elgin City | 5-7 | Arbroath | |
| Falkirk | 3-0 | Stirling Albion | |
| Forfar Athletic | 3-2 | Dunfermline Athletic | |
| Hamilton Academical | 0-1 | Airdrie United | |
| Montrose | 4-2 | Inverurie Locos | |
| Morton | 2-0 | Albion Rovers | |
| Peterhead | 1-2 | East Fife | |
| Stranraer | 1-2 | Stenhousemuir | |
| Wick Academy | 2-4 | Raith Rovers | |
» Scottish Challenge Cup 2012-2013 : Results
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