| P | W | D | L | F | A | GD | Pt | |
| Valencia | 6 | 3 | 3 | 0 | 8 | 4 | +4 | 12 |
| Bayern Munich | 6 | 2 | 3 | 1 | 7 | 6 | +1 | 9 |
| Rangers | 6 | 2 | 1 | 3 | 7 | 7 | 0 | 7 |
| PSV Eindhoven | 6 | 1 | 1 | 4 | 5 | 10 | -5 | 4 |
| Wednesday 15th September 1999 | |||
| Bayern Munich | 2-1 | PSV Eindhoven | |
| Valencia | 2-0 | Rangers | |
| Tuesday 21st September 1999 | |||
| PSV Eindhoven | 1-1 | Valencia | |
| Rangers | 1-1 | Bayern Munich | |
| Tuesday 28th September 1999 | |||
| Bayern Munich | 1-1 | Valencia | |
| PSV Eindhoven | 0-1 | Rangers | |
| Wednesday 20th October 1999 | |||
| Rangers | 4-1 | PSV Eindhoven | |
| Valencia | 1-1 | Bayern Munich | |
| Tuesday 26th October 1999 | |||
| PSV Eindhoven | 2-1 | Bayern Munich | |
| Rangers | 1-2 | Valencia | |
| Wednesday 3rd November 1999 | |||
| Bayern Munich | 1-0 | Rangers | |
| Valencia | 1-0 | PSV Eindhoven | |
September 1999
| Jul | Aug | Sep | Oct | Nov | Dec |
| Jan | Feb | Mar | Apr | May | Jun |
| Mo | Tu | We | Th | Fr | Sa | Su |
| 1 | 2 | 3 | 4 | 5 | ||
| 6 | 7 | 8 | 9 | 10 | 11 | 12 |
| 13 | 14 | 15 | 16 | 17 | 18 | 19 |
| 20 | 21 | 22 | 23 | 24 | 25 | 26 |
| 27 | 28 | 29 | 30 |
- Final
- Semi-Final
- Quarter-Final
- Second Round Group A
- Second Round Group B
- Second Round Group C
- Second Round Group D
- First Round Group A
- First Round Group B
- First Round Group C
- First Round Group D
- First Round Group E
- First Round Group F
- First Round Group G
- First Round Group H
- Third Qualifying Round
- Second Qualifying Round
- First Qualifying Round
