| Wednesday 7th November 2012 | |||
| First Round Group E | |||
| Chelsea | 3-2 | Shakhtar Donetsk | |
| Juventus | 4-0 | Nordsjaelland | |
| First Round Group F | |||
| Bayern Munich | 6-1 | Lille | |
| Valencia | 4-2 | BATE Borisov | |
| First Round Group G | |||
| Benfica | 2-0 | Spartak Moscow | |
| Celtic | 2-1 | Barcelona | |
| First Round Group H | |||
| CFR Cluj-Napoca | 1-3 | Galatasaray | |
| Sporting Braga | 1-3 | Manchester United | |
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