| Tuesday 24th September 2013 | |||
| Aston Villa | 0-4 | Tottenham Hotspur | |
| Burnley | 2-1 | Nottingham Forest | |
| Fulham | 2-1 | Everton | |
| Hull City | 1-0 | Huddersfield Town | |
| Leicester City | 2-1 | Derby County | |
| Manchester City | 5-0 | Wigan Athletic | |
| Southampton | 2-0 | Bristol City | |
| Sunderland | 2-0 | Peterborough United | |
| Swindon Town | 0-2 | Chelsea | |
| Watford | 2-3 | Norwich City | aet |
| West Ham United | 3-2 | Cardiff City | |
| Wednesday 25th September 2013 | |||
| Birmingham City | 3-1 | Swansea City | |
| Manchester United | 1-0 | Liverpool | |
| Newcastle United | 2-0 | Leeds United | |
| Tranmere Rovers | 0-2 | Stoke City | |
| West Bromwich Albion | 1-1 | Arsenal | aet |
| (Arsenal won on penalties) | |||
